## Abstract ^1^H, ^13^C and ^17^O NMR chemical shifts and ^__n__^__J__(H,H), ^1^__J__(C,H) and ^3^__J__(C‐6, H‐formyl) spin—spin coupling constants of chlorinated vanillins (3‐methoxy‐4‐hydroxybenzaldehydes) were determined. The variation in the long‐range ^4^__J__(H,H) value between the formyl pro
13C NMR studies of some hydroxycoumarins and related compounds
✍ Scribed by S. S. Sankar; R. D. Gilbert; R. E. Fornes
- Publisher
- John Wiley and Sons
- Year
- 1982
- Tongue
- English
- Weight
- 252 KB
- Volume
- 19
- Category
- Article
- ISSN
- 0749-1581
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✦ Synopsis
Abstract
The ^13^C chemical shifts and one‐bond carbon‐hydrogen coupling constants have been obtained for some hydroxycoumarins and their corresponding acetoxy and methoxy derivatives. The changes in the one‐bond carbon‐hydrogen coupling constants resulting from the conversion of a hydroxy group to an acetoxy group represent a simple method of assignment of the ^13^C NMR signals in coumarins which contain one or more hydroxy groups in the benzenoid ring.
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The =C chemical shifts and the carbon-proton coupling constants have been determined for some chlorinated isobutane and isobutene compounds. The one-bond coupling constants in isobutane derivatives showed a regular increase with an increasing number of y-chlorine substituents. The three-bond couplin
## Abstract The ^1^H and ^13^C chemical shifts, proton‐proton coupling constants, and one‐bond carbon‐hydrogen coupling constants have been obtained for 7‐azaindole, 1‐methyl‐7‐azaindole, their corresponding methyl iodide salts, and the related compound 7‐methyl‐7__H__‐pyrrolo [2,3‐__b__]pyridine.
## Abstract The ^13^C n.m.r. spectrum of benzofuroxan at −15°C is assigned on the basis of selective decoupling experiments and by comparison with the ^13^C chemical shifts of model compounds. The ^13^C spectra were also measured in trifluoroacetic acid as a solvent. From the temperature dependence
## Abstract The ^13^C NMR spectra of a series of methyl substituted 3‐arylpiperidines and 4‐aryl‐4‐piperidinols and related compounds are reported, and chemical shift data analysed in terms of the configuration and conformation of isomeric pairs. Special attention is given to the γ chemical shift p