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13C NMR spectra of wedeloside and related kaurenoid derivatives

✍ Scribed by I. A. S. Lewis; J. K. MacLeod

Publisher: John Wiley and Sons
Year: 1982
Tongue: English
Weight: 453 KB
Volume: 18
Category: Article
ISSN: 0749-1581
DOI: 10.1002/mrc.1270180305

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✦ Synopsis

Abstract

The ^13^C NMR spectra of the diterpenoid aminoglycoside wedeloside and certain of its derivatives, representatives of a new kaurenoid series, have been assigned. Shift calculations and labelling experiments have established a general substituent additivity relationship for chemical shifts in kaur‐16‐enes which allowed the reassignment of certain ^13^C resonances in the previously reported spectra of other kaur‐16‐enes.

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