## Abstract The carbon‐13 spectra of some __para__ and __meta__ substituted phenylferrocenes have been analysed. The substituent‐caused shifts are discussed and compared with similarly substituted biphenyls. Correlations with Hammett parameters and with the reactivity parameters of Swain and Lupton
13C NMR spectra of some N-aryl substituted sulphur–nitrogen compounds
✍ Scribed by G. Kresze; M. Berger; P. K. Claus; W. Rieder
- Publisher
- John Wiley and Sons
- Year
- 1976
- Tongue
- English
- Weight
- 281 KB
- Volume
- 8
- Category
- Article
- ISSN
- 0749-1581
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✦ Synopsis
Abstract
The ^13^C n.m.r. spectra of four classes of N‐aryl sulphur–nitrogen compounds are discussed. The para carbon shieldings of the N‐phenyl derivatives reflect the substituents effects of the various nitrogen groups. These show large differences for the four classes of compounds due to differences in the electronic structure of the sulphur–nitrogen bond.
📜 SIMILAR VOLUMES
## Abstract The ^13^C NMR spectra of some mono‐ and geminal disubstituted protoadamantanes have been assigned with the aid of shift reagents.
%S and I4N NMR spectra of nine sulphnr-nitrogen compounds are reported. It is demonstrated that "N NMR gives high signal-to-noise spectra with good discrimination of chemical shifts. It is concluded that both I4N and "S NMR can make a useful contribution to the study of sulphur-nitrogen chemistry an