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13C NMR spectra of natural products. 1—guaianolides

✍ Scribed by Antonio J. R. Da Silva; Marcos Garcia; Paul M. Baker; Jaime A. Rabi


Publisher
John Wiley and Sons
Year
1981
Tongue
English
Weight
403 KB
Volume
16
Category
Article
ISSN
0749-1581

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✦ Synopsis


Abstract

The ^13^C NMR spectra of 18 guaianolides have been measured and the chemical shifts assigned. The compounds investigated include the naturally occurring eremanthin (1), dehydrocostus lactone, eregoyazin, eregoyazidin and other semisynthetic lactones derived from 1. Qualitative analysis of the data suggests that the predominant conformation in almost all compounds so far studied is a distorted chair‐like form.


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