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13C NMR of camphene and α-pinene: Revised assignments

✍ Scribed by Werner Offermann

Publisher
John Wiley and Sons
Year
1982
Tongue
English
Weight
120 KB
Volume
20
Category
Article
ISSN
0749-1581

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✦ Synopsis

Abstract

The ^13^NMR signals of camphene (1) and α‐pinene (2) are reassigned unequivocally. J(CH) values of 1, 2, bornene, norbornene and norbornadiene are reported.

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Assignment of 13c chemical shifts in α-p
Assignment of 13c chemical shifts in α-pinene and pinanes following catalytic deuterium exchange
✍ David A. Forsyth; Sabri Mahmoud; Bill C. Giessen 📂 Article 📅 1982 🏛 John Wiley and Sons 🌐 English ⚖ 231 KB

## Abstract The ^13^C NMR chemical shifts of α‐pinene and __cis__‐ and __trans__‐pinanes have been reassigned on the basis of deuterium exchange experiments. Hydrogen at allylic positions in α‐pinene is exchanged for deuterium by treatment with D~2~ over an amorphous Pd‐Si alloy. Further reaction g