✦ LIBER ✦

13C NMR investigations of the ferroelectric phase transition of tris-sarcosine calcium chloride

✍ Scribed by D. Michel; F. Engelke

Publisher: Elsevier Science
Year: 1983
Tongue: English
Weight: 400 KB
Volume: 96
Category: Article
ISSN: 0009-2614
DOI: 10.1016/0009-2614(83)80690-3

No coin nor oath required. For personal study only.

✦ Synopsis

13 C IWR spectra were measured for tris-sarcosine calcium chloride (TSCC) crystals in ths par.xlectric phase (at temperatures of ==300 and 150 K) and in the ferroelectric phase (at temperatures of 119 K) by double-resonance techniques with proton decoupling. The ferrorlastic single crystals were rotated around their three cryst,4lographic axes to dcritc the tensors of magnetic shielding for the different carboxylic carbon atoms. There is no change of the ei~cnwluer and eisenvcctors of the tensors at the phase transition. The results arc consistent with the interpretation of former EPR data.

📜 SIMILAR VOLUMES

Raman scattering study of the ferroelect

Raman scattering study of the ferroelectric phase transition in tris-sarcosine calcium chloride (tscc)

✍ Louis-Claude Brunel; Jean-Claude Bureau; Siegfried Wartewig; Wolfgang Windisch 📂 Article 📅 1980 🏛 Elsevier Science 🌐 English ⚖ 235 KB

We obtained Raman scattermg spectra of normal and deuterated TSCC crystals and one TSCC,\_,B, mived crystal (Cl-x = Cl. Et, = Br). The soft-mode behavlour IS studted m the temperature range from 80 K to the Curie pomt. The Land T component of the soft mode are overdamped near 100 K whale the oblique

EPR investigations of critical order par

EPR investigations of critical order parameter fluctuations in ferroelectric tris-sarcosine calcium chloride (TSCC)

✍ R. Lippe; W. Windsch; G. Völkel; W. Schulga 📂 Article 📅 1976 🏛 Elsevier Science 🌐 English ⚖ 326 KB

ENDOR investigation of the polar structu

ENDOR investigation of the polar structure of tris-sarcosine calcium chloride

✍ H. Metz; R. Böttcher; W. Windsch 📂 Article 📅 1991 🏛 Elsevier Science 🌐 English ⚖ 426 KB

H and 13C ENDOR investigations on Mn-doped his-sarcosine calcium chloride (TSCC) and tris-sarcosine calcium bromide (TSCB) at 4.2 K revcal the polar structure of the calcium-(sarcosine)b complex in the ferroelectric phase of TSCC. The sarcosine molecules of type I do not change their position in the

Dielectric observation of a probably ant

Dielectric observation of a probably antiferroelectric high pressure phase in the ferroelectric Tris-Sarcosine Calcium Chloride (TSCC)

✍ V. Hugo Schmidt 📂 Article 📅 1980 🏛 Elsevier Science 🌐 English ⚖ 979 KB

Estimation of critical exponents for the

Estimation of critical exponents for the ferroelectric transition in Mn2+-doped tris-sarcosine calcium chloride (TSCC) by means of EPR

✍ W. Windsch; R. Lippe; G. Völkel 📂 Article 📅 1975 🏛 Elsevier Science 🌐 English ⚖ 249 KB

Nuclear quadrupole resonance of 35Cl in

Nuclear quadrupole resonance of 35Cl in the paraelectric phase of tri-sarcosine calcium chloride

✍ P.K. Kadaba; J. Pirnat; Z. Trontelj 📂 Article 📅 1975 🏛 Elsevier Science 🌐 English ⚖ 347 KB

The temperature dependence'of 35C1 pie nuckxu quadrupole resonaxe in tri-u&sine ulciuni chloride wb