## Abstract The one‐ and two‐bond ^13^C isotope shifts, typically −1.5 to −2.5 ppb and −0.7 ppb respectively, in non‐cyclic aliphatic systems and up to −4.4 ppb and −1.0 ppb in glucose cause effects that need to be taken into account in the adaptive NMR spectral library‐based quantification of the
✦ LIBER ✦
13C NMR chemical shifts of thiols, sulfinic acids, sulfinyl chlorides, sulfonic acids and sulfonic anhydrides
✍ Scribed by Fillmore Freeman; Christos N. Angeletakis
- Publisher
- John Wiley and Sons
- Year
- 1983
- Tongue
- English
- Weight
- 658 KB
- Volume
- 21
- Category
- Article
- ISSN
- 0749-1581
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✦ Synopsis
Abstract
^13^C NMR spectra of thiols, sulfinic acids, sulfinyl chlorides, sulfonic acids and sulfonic anhydrides have been obtained. The data are discussed in terms of the additivity of the deshielding effects exerted by the sulfur functionality at the α‐ or β‐position, and the shielding effects produced by the sulfur function at the γ‐position.
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