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13C and 1H NMR study of N-5′-methylsalicylideneanilines

✍ Scribed by K. Kishore; D. N. Sathyanarayana; V. A. Bhanu


Publisher
John Wiley and Sons
Year
1987
Tongue
English
Weight
297 KB
Volume
25
Category
Article
ISSN
0749-1581

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✦ Synopsis


The "C and 'H NMR spectra of six N-5'-methylsalicylideneanilines have been studied. Correlations of the chemical shifts of C-a (azomethine carbon) and C-4' with the cr, F, R , crI and a: parameters have been examined for N-5'-methylsalicylideneanilines, and also for N-benzylideneanilines and N-salicylideneanilines. The results suggest that the first compounds have a nearly planar conformation whereas the second and third type of derivatives have a twisted conformation.

KEY WORDS 13C and 'H NMR N-5'-methylsalicylideneanilines a, F and R, uI and a : Conformation.


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