## Abstract ^13^C, ^14^N and ^15^N NMR data are reported for some mesoionic 2,3‐diphenyltetrazoles with nitrogen‐containing exocyclic groups, and the data confirm their cyclic structures. The protonated forms of these mesoionic structures contain hydrogen atoms at the exocyclic groups.
13C and 15N NMR study of 2,3-diphenyltetrazolium-5-olate and 5-thiolate
✍ Scribed by W. Kozminski; J. Jazwinski; L. Stefaniak; G. A. Webb
- Publisher
- John Wiley and Sons
- Year
- 1990
- Tongue
- English
- Weight
- 213 KB
- Volume
- 28
- Category
- Article
- ISSN
- 0749-1581
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✦ Synopsis
Abstract
^13^C and ^15^N NMR chemical shifts are reported for 2,3‐diphenyltetrazolium‐5‐olate and ‐5‐thiolate and some of their derivatives. The data for N‐1 and C‐5 provide a very satisfactory means of distinguishing between O and S as the exocyclic substituent. The reported chemical shifts are consistent with the presence of the cyclic structures shown, rather than of the corresponding non‐cyclic structures.
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