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13C and 15N NMR chemical shifts of 1-(2′,4′-dinitrophenyl) and 1-(2′,4′,6′-trinitrophenyl) pyrazoles in the solid state and in solution

✍ Scribed by M. Ángeles García; Rosa M. Claramunt; José Elguero

Publisher
John Wiley and Sons
Year
2008
Tongue
English
Weight
107 KB
Volume
46
Category
Article
ISSN
0749-1581

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✦ Synopsis

Abstract

The ^13^C and ^15^N CPMAS NMR spectra of 18 pyrazoles substituted at position 1 by dinitrophenyl and trinitrophenyl (picryl) groups have been recorded. To help in the assignments, some of these compounds were studied in DMSO‐d~6~ solution. Phenomena such as the conformation of the N‐aryl groups and broadening of splittings due to quadrupolar nuclei are discussed. Copyright © 2008 John Wiley & Sons, Ltd.

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