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13C and 14C kinetic isotope effects in the catalytic oxidation of CO over NiO catalyst

✍ Scribed by I. Kobal; M. Senegačnik; H. Kobal

Book ID: 113175665
Publisher: Elsevier Science
Year: 1977
Tongue: English
Weight: 522 KB
Volume: 49
Category: Article
ISSN: 0021-9517
DOI: 10.1016/0021-9517(77)90235-4

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## Abstract The kinetic isotope effects in the reaction of methane (CH~4~) with Cl atoms are studied in a relative rate experiment at 298 ± 2 K and 1013 ± 10 mbar. The reaction rates of ^13^CH~4~, ^12^CH~3~D, ^12^CH~2~D~2~, ^12^CHD~3~, and ^12^CD~4~ with Cl radicals are measured relative to ^12^CH~