This short note describes studies of the pyrolysis of methacrylonitrile over a wide range of temperatures under flowing nitrogen at atmospheric pressure. Hydrogen cyanide was not found to be a primary product, but several organic nitriles are formed which decompose at higher temperature ( > 1100 K)
136. On the mechanism of surface carbon formation during the pyrolysis of benzene in the presence of hydrogen
β Scribed by Alberto I. Lacava; Maritza Caraballo
- Publisher
- Elsevier Science
- Year
- 1982
- Tongue
- English
- Weight
- 126 KB
- Volume
- 20
- Category
- Article
- ISSN
- 0008-6223
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Ethylene a t concentrations of 2.7 X to 1.0 x mol L ' has been pyrolyzed at 900 K in a flow system. The products ethane and hydrogen have been analyzed by gas chromatography. The results are consistent with a mechanism in which these products are initially formed as follows: L11 141 Reaction [11 o
## Abstract A detailed radical reaction model, both homogeneous and heterogeneous, is shown to describe quantitatively published initial rates of the pyrolysis of 1,2βdichloroethane in the gas phase. These data were obtained in conditioned static reactors with different surfaceβtoβvolume ratios, in
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