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Mechanism of the pyrolysis of 1,2-dichloroethane in the absence and presence of added chlorine

✍ Scribed by G. Huybrechts; G. Wouters

Publisher: John Wiley and Sons
Year: 2002
Tongue: English
Weight: 128 KB
Volume: 34
Category: Article
ISSN: 0538-8066
DOI: 10.1002/kin.10052

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✦ Synopsis

Abstract

A detailed radical reaction model, both homogeneous and heterogeneous, is shown to describe quantitatively published initial rates of the pyrolysis of 1,2‐dichloroethane in the gas phase. These data were obtained in conditioned static reactors with different surface‐to‐volume ratios, in the absence (at 703 K) and presence (at 572 K) of chlorine. The pressures of 1,2‐dichloroethane and chlorine vary from 20 to 500 torr and from 0 to 16 torr, respectively. © 2002 Wiley Periodicals, Inc. Int J Chem Kinet 34: 316–321, 2002

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