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1,3,5-Triacetyl-2,4,6-triphenylbenzene: a sterically hindered molecule

โœ Scribed by Booth, B. L. ;Pritchard, R. G. ;Taylor-Gomes, J.

Book ID
114510239
Publisher
International Union of Crystallography
Year
1993
Tongue
English
Weight
344 KB
Volume
49
Category
Article
ISSN
0108-2701

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Our study demonstrated that 4-(4,6-dimethoxy-1,3,5-triazine-2-yl)-4-methyl-morpholinium chloride (DMTMM) is a versatile coupling reagent for the synthesis of sterically-hindered peptidomimetics. It is superior to HBTU/HOBt and CDMT in controlling racemization and N-arylation, respectively.