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1,3-Shifts. II. The Stereochemistry of the Rearrangement of α-Alkoxystyrenes 1

✍ Scribed by Wiberg, Kenneth B.; Rowland, Bertram I.


Book ID
126849930
Publisher
American Chemical Society
Year
1955
Tongue
English
Weight
656 KB
Volume
77
Category
Article
ISSN
0002-7863

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Stereochemistry of the 1,2-Wittig rearra
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The [1,2] Wittig rearrangement of P-alkoxyalkyl ally1 ethers has been studied and found to provide syn-1,3-diol derivatives in 14-32% yield and with useful levels of diastereoselection. The rearrangement of a-metalated ethers (Wittig rearrangement) has been of interest to investigators since its di