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1,3-Dipolar Cycloaddition Reaction of d -Glucose-Derived Nitrone with Allyl Alcohol: Synthesis of 2-Hydroxy-1-deoxycastanospermine Analogues

✍ Scribed by Karanjule, Narayan S.; Markad, Shankar D.; Sharma, Tarun; Sabharwal, Sushma G.; Puranik, Vedavati G.; Dhavale, Dilip D.


Book ID
127185269
Publisher
American Chemical Society
Year
2005
Tongue
English
Weight
221 KB
Volume
70
Category
Article
ISSN
0022-3263

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Regio- and stereoselective synthesis of
✍ Hong-Kui Zhang; Wing-Hong Chan; Albert W. M. Leeb; Wai-Yeung Wong πŸ“‚ Article πŸ“… 2008 πŸ› Journal of Heterocyclic Chemistry 🌐 English βš– 445 KB πŸ‘ 1 views

## Abstract magnified image Asymmetric 1,3‐dipolar cycloadditions of chiral nitrones to 1‐propene‐1,3‐sultone (**1**) were investigated. Chiral nitrones **6a‐e** reacted with sultone **1** in toluene at 90 Β°C for 24‐36 h to give the corresponding isoxazolidines in moderate yields with high regiose