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1,3-Diphenylpropane-1,3-diamines XII [1]. A Novel Approach to Stereodefined Oximes and Oxime Ethers of Monothioketalized 1,3-Diketones and their Conversion to 3-Aminooximes

✍ Scribed by Alexander Kaiser; Wolfgang Wiegrebe


Book ID
105749288
Publisher
Springer Vienna
Year
1998
Tongue
English
Weight
258 KB
Volume
129
Category
Article
ISSN
0026-9247

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Synthesis of oximes, conversion to nitri
✍ BΓ©atrice Touaux; FranΓ§oise Texier-Boullet; Jack Hamelin πŸ“‚ Article πŸ“… 1998 πŸ› John Wiley and Sons 🌐 English βš– 147 KB πŸ‘ 2 views

Aldoximes and ketoximes were readily synthesized from aldehydes and hydroxylamine hydrochloride on Al 2 O 3 without solvent under microwave irradiation. At higher irradiation power, aldoximes dehydrated to nitriles and ketoximes rearranged to amides. Aldoximes reacted in a one-pot reaction with Nchl