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1,3-dinitroso-, 1-nitroso-3-nitro-, and 1,3-dinitro-1,3-diazacycloalkanes. A multinuclear NMR study

✍ Scribed by Rodney L. Willer; Donald W. Moore

Publisher
John Wiley and Sons
Year
1988
Tongue
English
Weight
624 KB
Volume
26
Category
Article
ISSN
0749-1581

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✦ Synopsis

A series of five-, six-, and seven-membered 1,3-dinitroso-, l-nitroso-3-nitro-, and 1,3-dinitro-1,3-diazacycloalkanes were investigated by 'H, I3C, and "N NMR spectroscopy. Hindered rotation of the nitrosamine group leads to the existence of rotational isomers. The relative populations of rotamer forms are determined by steric and electrostatic interactions between nitroso groups and the remainder of the molecule, and by the size of the ring.

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