𝔖 Bobbio Scriptorium
✦   LIBER   ✦

1,3-Asymmetric induction in enolate alkylation reactions of N-protected γ-amino acid derivatives

✍ Scribed by Stephen Hanessian; Robert Schaum


Publisher
Elsevier Science
Year
1997
Tongue
French
Weight
239 KB
Volume
38
Category
Article
ISSN
0040-4039

No coin nor oath required. For personal study only.


📜 SIMILAR VOLUMES


1,3-Asymmetric induction in dianionic al
✍ Stephen Hanessian; Roberto Margarita 📂 Article 📅 1998 🏛 Elsevier Science 🌐 French ⚖ 255 KB

Dianions derived from N-Cbz and N-Boc glutamic acid esters undergo highly stereoselective anti allylation reactions at C-4. The roles of protecting groups and of the electrophile were studied. Synthetic applications and potential utility in peptidomimetic design are also described.

1,2-Asymmetric induction in dianionic al
✍ Stephen Hanessian; Roberto Margarita; Adrian Hall; Xuehong Luo 📂 Article 📅 1998 🏛 Elsevier Science 🌐 French ⚖ 260 KB

Dianions derived from N-Cbz aspartic acid esters undergo highly stereoselective ant/ allylation reactions at the unsubstituted carbon. The roles of additives, of the cation and of the electrophile were studied Synthetic applications and potential utility in peptidomimetic design are also described.