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1,2-Asymmetric induction in radical reactions of β-amino acid derivatives

✍ Scribed by E. Peter Kündig; Long-He Xu; Patrick Romanens


Publisher
Elsevier Science
Year
1995
Tongue
French
Weight
201 KB
Volume
36
Category
Article
ISSN
0040-4039

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1,2-Asymmetric induction in dianionic al
✍ Stephen Hanessian; Roberto Margarita; Adrian Hall; Xuehong Luo 📂 Article 📅 1998 🏛 Elsevier Science 🌐 French ⚖ 260 KB

Dianions derived from N-Cbz aspartic acid esters undergo highly stereoselective ant/ allylation reactions at the unsubstituted carbon. The roles of additives, of the cation and of the electrophile were studied Synthetic applications and potential utility in peptidomimetic design are also described.