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129Xe NMR for the study of oxidized and reduced AgX zeolites

โœ Scribed by A. Gedeon; R. Burmeister; R. Grosse; B. Boddenberg; J. Fraissard


Publisher
Elsevier Science
Year
1991
Tongue
English
Weight
321 KB
Volume
179
Category
Article
ISSN
0009-2614

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## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 200 leading journals. To access a ChemInform Abstract, please click on HTML or PDF.

129Xe NMR of xenon adsorbed on zeolites:
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experiments we have determined values of the mean free path 1 of xenon adsorbed on various zeolites. We deduce from them the dependence of the chemical shift S on 1. It is now possible to determine the dimensions of any cavity in which xenon can be adsorbed.

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The adsorption isotherms and lz9Xe NMR chemical shifts of xenon in the voids of zeolite Y with O%, 53%, 75%, and 95% exchange of copper (II) for sodium ions were determined. With increasing copper content the shifts go uptield. The local chemical shifts of xenon at a crystallographic SII site with a