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[(1,2,5,6-η)-1,3,5,7-Cyclooctatetraene]iodido(methyl)platinum(II)

✍ Scribed by Song, Ah-Ran ;Hwang, In-Chul ;Ha, Kwang

Publisher
International Union of Crystallography
Year
2007
Tongue
English
Weight
967 KB
Volume
63
Category
Article
ISSN
1600-5368

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✦ Synopsis

In the title complex, [Pt(CH 3 )I(C 8 H 8 )], the Pt II centre lies in a square-planar environment defined by the I and methyl C atoms and the mid-points of the two -coordinated double bonds of 1,3,5,7-cyclooctatetraene. Because of the different trans influences of the I atom and the methyl group, the Pt-C bonds trans to the methyl group are longer than those trans to the I atom.

Related literature

For a related structure, see: Song et al. (2006). Experimental Crystal data [Pt(CH 3 )I(C 8 H 8 )] M r = 441.17 Monoclinic, P2 1 =c a = 8.447 (2) A b = 10.181 (2) A c = 13.504 (2) A = 120.901 (3) V = 996.5 (3) A ˚3 Z = 4 Mo K radiation = 17.12 mm À1 T = 293 (2) K 0.18 Â 0.17 Â 0.10 mm Data collection Bruker SMART 1000 CCD diffractometer Absorption correction: multi-scan (SADABS; Bruker, 2000) T min = 0.063, T max = 0.181 5241 measured reflections 2034 independent reflections 1824 reflections with I > 2(I) R int = 0.031 Refinement R[F 2 > 2(F 2 )] = 0.035 wR(F 2 ) = 0.095 S = 1.04 2034 reflections

📜 SIMILAR VOLUMES

Chlorido[(1,2,5,6-η)-1,3,5,7-cyclooctate
Chlorido[(1,2,5,6-η)-1,3,5,7-cyclooctatetraene]phenylplatinum(II)
✍ Song, Ah-Ran ;Hwang, In-Chul ;Ha, Kwang 📂 Article 📅 2007 🏛 International Union of Crystallography 🌐 English ⚖ 899 KB

In the title complex, [Pt(C 6 H 5 )Cl(C 8 H 8 )], the Pt II centre lies in a square-planar environment defined by the Cl and -bonded phenyl C atoms and the mid-points of the two -coordinated double bonds of 1,3,5,7-cyclooctatetraene. Because of the different trans influences of the Cl atom and the p