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1,2,4-Oxadiazoles. XI. An intermediate in the isomerization from nitrones to amides

✍ Scribed by L. Baiocchi; G. Picconi; G. Palazzo


Book ID
112125839
Publisher
Journal of Heterocyclic Chemistry
Year
1979
Tongue
English
Weight
214 KB
Volume
16
Category
Article
ISSN
0022-152X

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Evidence for a ladenburg benzene interme
✍ Edward M. Arnett; J.Martin Bollinger πŸ“‚ Article πŸ“… 1964 πŸ› Elsevier Science 🌐 French βš– 263 KB

1,2,4,5-Tetra-l-butylbenzene (394) (TTBB) is believed to be a highly strained boat-shaped molecule (4) (I) and so might be expected to undergo photoisomerisation to a Dewar benzene (II) more readily than does 1,2,4-trit-butylbenzene(5'6), which was the first compound reported to undergo such a conve