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Mechanism of the isomerization of 1,5,9-cyclododecatriyne to hexaradialene: 1,2:3,4:5,6-tricyclobutabenzene is not an intermediate

✍ Scribed by Dower, William V.; Vollhardt, K. Peter C.


Book ID
118029394
Publisher
American Chemical Society
Year
1982
Tongue
English
Weight
281 KB
Volume
104
Category
Article
ISSN
0002-7863

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1,2,4,5-Tetra-l-butylbenzene (394) (TTBB) is believed to be a highly strained boat-shaped molecule (4) (I) and so might be expected to undergo photoisomerisation to a Dewar benzene (II) more readily than does 1,2,4-trit-butylbenzene(5'6), which was the first compound reported to undergo such a conve