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1,2-Stereoinduction in Radicals and Anions: A comparison between hydrogen abstraction and protonation

✍ Scribed by Peter Erdmann; Jörg Schäfer; Ronald Springer; Heinz-Georg Zeitz; Bernd Giese

Publisher
John Wiley and Sons
Year
1992
Tongue
German
Weight
365 KB
Volume
75
Category
Article
ISSN
0018-019X

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✦ Synopsis

The observed product ratio is the result of kinetic control, because isomerization under the conditions of the experiments could not be observed.

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✍ Á. Gedra; J. Lukács; T. Vidóczy; L. Sümegi; D. Gál 📂 Article 📅 1986 🏛 John Wiley and Sons 🌐 English ⚖ 334 KB

Hydrogen abstraction by 1-phenylethyl radicals (RH) from phenylmethyl-carbinol (HROH) and benzyl alcohol (H2R'OH) has been studied in the liquid phase at 120°C. 1-Phenylethyl radicals have been generated by thermal decomposition of azo-bis-lphenyl ethane and the formation of ethylbenzene (RH2), acet