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ChemInform Abstract: 1,2-Shifts of Hydrogen Atoms in Aryl Radicals.

✍ Scribed by Michele A. Brooks; Lawrence T. Scott

Publisher
John Wiley and Sons
Year
2010
Weight
23 KB
Volume
30
Category
Article
ISSN
0931-7597

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An excellent substrate of methylmalonyl-CoA mutase, methylmalonyl-carba-(dethia) coenzyme A (methylmalonyl-CH(2)-CoA), was synthesized by a chemoenzymatic method and its alpha-proton was exchanged with deuterium by long-term incubation in deuterium oxide at pH 6.9. After addition of highly purified