1.2-Dioxan
✍ Scribed by Criegee, Rudolf ;Müller, Gerhard
- Publisher
- Wiley (John Wiley & Sons)
- Year
- 1956
- Tongue
- English
- Weight
- 205 KB
- Volume
- 89
- Category
- Article
- ISSN
- 0009-2940
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## Abstract It is shown that 2‐vinyl‐1,3‐dioxan can be synthesized by the methods of __Faass__ and __Hilgert__^1^ and of __Fisher__ and __Smith__^2^. From 2‐vinyl‐1,3‐dioxan we obtained 2‐ethyl‐1,3‐dioxan and 2‐(1′,2′‐dibromoethyl)‐1,3‐dioxan. 4‐Vinyl‐1,3‐dioxan and 2‐vinyl‐1,3‐dioxan have the same
Single-crystal X-ray study T = 153 K Mean '(C±C) = 0.003 A Ê R factor = 0.041 wR factor = 0.121 Data-to-parameter ratio = 11.2 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.
Copolymers of the cyclic ketene acetals, 2-methylene-5,5-dimethyl-1,3-dioxane, 3, (MJ with 2-methylene-l,3-dioxolane, 4, (M2) or 2-methylene-1,3-dioxane, 5, (M2), were synthesized by cationic copolymerization. An experimental method was designed to study the reactivity of these very reactive and ext