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1,2-Bis­(di­tolyl­phosphino)­ethane

✍ Scribed by Zeller, Matthias ;Lazich, Evelyn ;Wagner, Timothy R. ;Hunter, Allen D.

Publisher
International Union of Crystallography
Year
2003
Tongue
English
Weight
257 KB
Volume
59
Category
Article
ISSN
1600-5368

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Single-crystal X-ray study T = 295 K Mean '(C±C) = 0.006 A Ê R factor = 0.052 wR factor = 0.182 Data-to-parameter ratio = 18.1 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.

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[Bis­(di­phenyl­phosphino)­ethane-P,P′)][bis­(di­phenyl­phosphino)­ethane sulfide-P)]­(thio­benzoato-S)copper(I)
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The crystal structure of the title compound, [(dppe-P,P H )Cu-(dppeS-P)(SC{O}Ph)], [Cu(C 7 H 5 OS)(C 26 H 24 P 2 S)(C 26 H 24 P 2 )], is reported. In this monomeric compound, the Cu atom has a tetrahedral coordination geometry, with a P 3 CuS core.