The title compound, C 26 H 30 B 10 P 2 , was synthesized by the reaction of 1,2-dilithiocarborane with diphenylchorophosphine in diethyl ether. The molecular symmetry of the molecule deviates from C 2v because of the different mutual orientations of the phenyl groups. The two P atoms of the -PPh 2 g
1,2-Bis(dicyclohexylphosphino)-1,2-dicarba-closo-dodecaborane
✍ Scribed by Su, Fang-Fang ;Dou, Jian-Min ;Li, Da-Cheng ;Wang, Da-Qi
- Publisher
- International Union of Crystallography
- Year
- 2007
- Tongue
- English
- Weight
- 765 KB
- Volume
- 63
- Category
- Article
- ISSN
- 1600-5368
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The title compound, [Ag 2 Cl 2 (C 26 H 30 B 10 P 2 ) 2 ]Á2CH 2 Cl 2 , was synthesized by the reaction of 1,2-bis(dipenylphosphino)-1,2dicarba-closo-dodecaborane with AgCl in ethanol. The diphosphino-closo-carborane ligand is coordinated in a bidentate manner to the Ag atom through the two P atoms. T