1,2-Bis[5-oxo-3-(n-propyl)-4,5-dihydro-3H-1,2,4-triazol-4-yl]ethane dihydrate
✍ Scribed by Özdemir, Gonca ;Işık, Şamil ;Sancak, Kemal ;Şaşmaz, Selami ;Okumuşoğlu, Nazmi Turan
- Publisher
- International Union of Crystallography
- Year
- 2005
- Tongue
- English
- Weight
- 256 KB
- Volume
- 61
- Category
- Article
- ISSN
- 1600-5368
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📜 SIMILAR VOLUMES
The title compound, C 20 H 14 N 12 S 2 , was synthesized by the reaction of 3-hydrazino-1H-1,2,4-triazole with phenyl isocyanate in benzene and by ring closure in an alkaline medium. Intermolecular N-HÁ Á ÁN hydrogen bonds are observed and these form a five-membered ring.
In the title compound, C 15 H 14 N 4 OÁ2H 2 O, the 1,2,4-triazole, pyridine and benzene rings do not share a common plane. The crystal structure is stabilized by O-HÁ Á ÁN and O-HÁ Á ÁO intermolecular hydrogen-bond interactions.
## Abstract magnified image One‐pot reaction of 3‐aryl‐5‐methyl‐1,3,4‐oxadiazolin‐2‐ones **1a‐g** with ethanolamine yielded the 4‐(2‐hydroxyethyl)‐2‐aryl‐5‐methyl‐2,4‐dihydro‐3__H__‐1,2,4‐triazolin‐3‐ones **2a‐g** which were converted to the azido compounds **6a‐g**. These azides on 1,3‐dipolar cy
In the title compound, C 15 H 19 N 5 OS, the morpholine ring adopts a chair conformation. The mean plane of the pyridine ring makes a dihedral angle of 35.16 (7) with the triazole ring plane.