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1,2-Anionic rearrangements in the gas phase. The (acyloxy)acetate-acylhydroxyacetate and related rearrangements

โœ Scribed by Eichinger, Peter C. H.; Hayes, Roger N.; Bowie, John H.

Book ID
126201511
Publisher
American Chemical Society
Year
1991
Tongue
English
Weight
589 KB
Volume
113
Category
Article
ISSN
0002-7863

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The [Mโˆ’Hโˆ’CO2]โˆ’ anion from glycyl glycine
The [Mโˆ’Hโˆ’CO2]โˆ’ anion from glycyl glycine undergoes rearrangement in the gas phase
โœ Michelle L. Styles; Richard A. J. Oโ€™Hair ๐Ÿ“‚ Article ๐Ÿ“… 1998 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 188 KB

The [Mร€Hร€CO 2 ] ร€ anion derived from collision induced loss of CO 2 from the [Mร€H] ร€ ion of glycyl glycine has been examined using various tandem mass spectrometry (MS/MS) experiments. Using 15 N isotopically labelled glycyl glycine, these MS/MS experiments reveal that the initially formed carbanion