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Molecular Rearrangement in the Gas Phase Photolysis of 1-Phenyl-2-butene

✍ Scribed by Comtet, M.


Book ID
126043045
Publisher
American Chemical Society
Year
1969
Tongue
English
Weight
256 KB
Volume
91
Category
Article
ISSN
0002-7863

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Low fluence (25 mJ.cm Β°2) and high fluence (180 mJ.cm -2) ArF laser (193.3 nm) photolysis of R1C(O)R 2, (R 1, R 2 = CH3, C2H5, C2H3) afford carbon monoxide and hydrocarbons vVnich are in the former case mostly R1-R 2 alkanes and in the latter case R1-R 2 alkanes along with methane, ethene and ethyne