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1,2- and 1,4-Naphthoquinones: general synthesis of benzo[b]naphtho[2,3-d]furan-6,11-diones

✍ Scribed by Ana Martı́nez; Juan C Estévez; Ramón J Estévez; Luis Castedo

Publisher
Elsevier Science
Year
2000
Tongue
French
Weight
81 KB
Volume
41
Category
Article
ISSN
0040-4039

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✦ Synopsis

A new general synthesis of benzo[b]naphtho[2,3-d]furan-6,11-diones starting from readily available 2-(2 -oxo-3 -phenylpropyl)benzaldehydes is described.

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The electrochemical reductions of 9 benzo[b]naphtho[2,3-dlfuran-6,l I-dione derivatives in dimethylformamide were investigated. In the aprotic medium the quinones reduced in two successive one-electron steps. The influence of molecular structure on reduction potential is addressed. The reduction pro