The complex W (CO) 5 ( C02) has been observed in the gas phase by time-resolved infrared spectroscopy following 355 nm laser photolysis of W (CO)6 in the presence of CO,. The complex was shown to be in equilibrium with its precursor W (CO) s at room temperature and the bond energy for binding of CO2
113. The CO/CO2 ratio and surface complex formation for oxygen and steam reactions with carbon
β Scribed by J Dollimore; J Bailey; B.H Harrison; S.S Barton
- Publisher
- Elsevier Science
- Year
- 1973
- Tongue
- English
- Weight
- 109 KB
- Volume
- 11
- Category
- Article
- ISSN
- 0008-6223
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π SIMILAR VOLUMES
Density functional theory was used to investigate the chemical reactivity of oxygen vacancies on the MgO surface towards CO 2 , NO 2 and metal atoms. The oxygen vacancies induce changes in the electronic structure of the MgO compared to that of the regular surface. The most common surface defects ca
## Abstract The gasβphase reactions of hydrated electrons with carbon dioxide and molecular oxygen were studied by Fourier transform ion cyclotron resonance (FTβICR) mass spectrometry. Both CO~2~ and O~2~ react efficiently with (H~2~O)~__n__~^β^ because they possess lowβlying empty Ο\* orbitals. Th