𝔖 Bobbio Scriptorium
✦   LIBER   ✦

1,1,2-Trichloro-4,4-bis(4-methylphenylsulfanyl)-3-nitrobuta-1,3-diene

✍ Scribed by Ibis, Cemil ;Deniz, N. Gulsah


Publisher
International Union of Crystallography
Year
2007
Tongue
English
Weight
385 KB
Volume
63
Category
Article
ISSN
1600-5368

No coin nor oath required. For personal study only.

✦ Synopsis


The title compound, C~18~H~14~Cl~3~NO~2~S~2~, was synthesized by the reaction of 1,1,2,4-tetrachloro-4-(4-methylphenylsulfanyl)-3-nitrobuta-1,3-diene with ethanedithiol. The butadiene unit is not completely planar as would be expected if the two double bonds were fully conjugated The torsion angle of the butadiene unit is −82.2 (5)°.


📜 SIMILAR VOLUMES


1,1-Dichloro-3-(6,1,3-oxadithiaoctocan-2
✍ Ibis, Cemil ;Deniz, N. Gulsah 📂 Article 📅 2007 🏛 International Union of Crystallography 🌐 English ⚖ 757 KB

The molecule of the title compound, C 15 H 15 Cl 2 NO 3 S 3 , is not planar. The butadiene group and the 4-methylphenyl ring are inclined at an angle of 57.9 (1) . ## Related literature For general background, see: Edema et al.

1,5-Bis(3,4-dimethoxyphenyl)penta-1,4-di
✍ Butcher, Ray J. ;Jasinski, Jerry P. ;Yathirajan, H. S. ;Bindya, S ;Narayana, B. 📂 Article 📅 2007 🏛 International Union of Crystallography 🌐 English ⚖ 854 KB

The title compound, C 21 H 22 O 5 , a derivative of the antioxidant, anti-inflammatory compound curcumin, crystallizes with two molecules (A and B) in the asymmetric unit. The mean planes of the two 3,4-dimethoxyphenyl groups in A and B make dihedral angles of 57.9 (7) and 33.4 (3) . An extensive ne

ChemInform Abstract: A New Synthesis of
✍ N. ONO; K. MATSUMOTO; T. OGAWA; H. TANI; H. UNO 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 28 KB 👁 2 views

A New Synthesis of 1-Phenylthio-and 1-Alkylamino-4-nitrobuta-1,3dienes. -A simple method for the synthesis of 1-phenylthiobutadiene (VII) from acrolein and its conversion into 1-alkylaminobutadienes (IX) is described. Moreover, preliminary results of the nonlinear optical activity of these new push