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11,12-Bis(2,2-dimethyl­prop­yl)-9,10-dihydro-9,10-ethenoanthracene

✍ Scribed by Herres, Joseph P. ;Forman, Mark A. ;Wheeler, Kraig A.

Publisher
International Union of Crystallography
Year
2005
Tongue
English
Weight
268 KB
Volume
61
Category
Article
ISSN
1600-5368

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✦ Synopsis

The title compound, C 26 H 32 , was retrieved as one of three products from the reaction of tert-butyllithium with 11,12dimethylene-9,10-dihydroethenoanthracene and 4,5-diiodopentacyclo[4.3.0.0 2,4 .0 3,8 .0 5,7 ]nonane. The structure shows the expected ethenoanthracene geometry with molecules arranged via van der Waals surfaces.

📜 SIMILAR VOLUMES

11-(2,2-Dimethylpropyl)-12-{2-[12-(2,2-d
11-(2,2-Dimethylpropyl)-12-{2-[12-(2,2-dimethylpropyl)-9,10-dihydro-9,10-ethenoanthracen-11-yl]ethyl}-9,10-dihydro-9,10-ethenoanthracene
✍ Herres, Joseph P. ;Forman, Mark A. ;Wheeler, Kraig A. ;Yap, Glenn P. A. 📂 Article 📅 2005 🏛 International Union of Crystallography 🌐 English ⚖ 312 KB

Reaction of tert-butyllithium with 11,12-dimethylene-9,10dihydro-9,10-ethanoanthracene and 4,5-diiodopentacyclo-[4.3.0.0 2,4 .0 3,8 .0 5,7 ]nonane gives three products, one of which crystallizes from petroleum ether as the title compound, C 44 H 46 , (I). Molecules of (I) are positioned on inversion

Photochemistry of 11,12-bis(Aminomethyl)
Photochemistry of 11,12-bis(Aminomethyl)-9,10-dihydro-9,10-ethenoanthracene in Solution and in the Solid State
✍ Scheffer, John R. ;Ihmels, Heiko 📂 Article 📅 1997 🏛 John Wiley and Sons 🌐 English ⚖ 513 KB

## Abstract The photochemistry of 11,12‐bis(aminomethyl)‐9,10‐dihydro‐9,10‐ethenoanthracene (4) was investigated in solution and in the solid state. Direct irradiation of 4 gave the singlet state photoproduct 5, whereas the triplet derived photoproduct could only be obtained by irradiating the bis(