𝔖 Bobbio Scriptorium
✦   LIBER   ✦

11-(2,2-Dimethylpropyl)-12-{2-[12-(2,2-dimethylpropyl)-9,10-dihydro-9,10-ethenoanthracen-11-yl]ethyl}-9,10-dihydro-9,10-ethenoanthracene

✍ Scribed by Herres, Joseph P. ;Forman, Mark A. ;Wheeler, Kraig A. ;Yap, Glenn P. A.

Publisher
International Union of Crystallography
Year
2005
Tongue
English
Weight
312 KB
Volume
61
Category
Article
ISSN
1600-5368

No coin nor oath required. For personal study only.

✦ Synopsis

Reaction of tert-butyllithium with 11,12-dimethylene-9,10dihydro-9,10-ethanoanthracene and 4,5-diiodopentacyclo-[4.3.0.0 2,4 .0 3,8 .0 5,7 ]nonane gives three products, one of which crystallizes from petroleum ether as the title compound, C 44 H 46 , (I). Molecules of (I) are positioned on inversion centers (Z 0 = 0.5) in the space group P2 1 /n and lack any discernible intermolecular interactions.

πŸ“œ SIMILAR VOLUMES

11,12-Bis(2,2-dimethylΒ­propΒ­yl)-9,10-dih
11,12-Bis(2,2-dimethylΒ­propΒ­yl)-9,10-dihydro-9,10-ethenoanthracene
✍ Herres, Joseph P. ;Forman, Mark A. ;Wheeler, Kraig A. πŸ“‚ Article πŸ“… 2005 πŸ› International Union of Crystallography 🌐 English βš– 268 KB

The title compound, C 26 H 32 , was retrieved as one of three products from the reaction of tert-butyllithium with 11,12dimethylene-9,10-dihydroethenoanthracene and 4,5-diiodopentacyclo[4.3.0.0 2,4 .0 3,8 .0 5,7 ]nonane. The structure shows the expected ethenoanthracene geometry with molecules arran

Photochemistry of 11,12-bis(Aminomethyl)
Photochemistry of 11,12-bis(Aminomethyl)-9,10-dihydro-9,10-ethenoanthracene in Solution and in the Solid State
✍ Scheffer, John R. ;Ihmels, Heiko πŸ“‚ Article πŸ“… 1997 πŸ› John Wiley and Sons 🌐 English βš– 513 KB

## Abstract The photochemistry of 11,12‐bis(aminomethyl)‐9,10‐dihydro‐9,10‐ethenoanthracene (4) was investigated in solution and in the solid state. Direct irradiation of 4 gave the singlet state photoproduct 5, whereas the triplet derived photoproduct could only be obtained by irradiating the bis(