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1,1,1-Tris(diphenylphosphinemethyl)ethane complexes of nickel and platinum with tin

✍ Scribed by Evilázio F. Assis; Carlos A. L. Filgueiras

Publisher
Springer
Year
1994
Tongue
English
Weight
283 KB
Volume
19
Category
Article
ISSN
0340-4285

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✦ Synopsis

This paper describes a series of bimetallic compounds derived from the starting complexes [Ni(tdpme)C12] and [Pt(tdpme)C121 [where tdpme = 1,1,1-tris(diphenylphosphinemethyl) ethane, MeC(CH2PPhz)3] upon reaction with Ph3SnC1 and NaBH~, as well as with SnC12. In the first case, a direct bond between tin and the transition metal is formed (with concomitant reduction to the 1 + oxidation state for the nickel species), whereas SnC12 forms chlorine bridges with the transition metals.

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