1-Undecyl-4,7-diaza-1-azoniatricyclo[5.2.1.04,10]decane iodide
✍ Scribed by Battle, Andrew R. ;Martin, Lisandra L.
- Book ID
- 104487636
- Publisher
- International Union of Crystallography
- Year
- 2006
- Tongue
- English
- Weight
- 242 KB
- Volume
- 62
- Category
- Article
- ISSN
- 1600-5368
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## Synthesis of 2-Azatricyclo(5.2.1.04,10)decanes and 2,5-Diazatricyclo(5. 2.1.04,10)decanes by Intramolecular Azomethine Ylide Cycloadditions. -The title reaction proceeds stereoselectively with all-cis stereochemistry of the products, which are of interest in natural product synthesis and medic
The title compound, a 1:2 adduct of 18-crown-6 and ammonia, C 12 H 24 O 6 Á2NH 3 , has inversion symmetry. Two ammonia molecules are connected to the crown ether above and below the cyclic plane via N-HÁ Á ÁO hydrogen bonds to form a disclike adduct.