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ChemInform Abstract: Synthesis of 2-Azatricyclo(5.2.1.04,10)decanes and 2,5-Diazatricyclo(5. 2.1.04,10)decanes by Intramolecular Azomethine Ylide Cycloadditions.

✍ Scribed by L. E. OVERMAN; J. E. TELLEW

Publisher: John Wiley and Sons
Year: 2010
Weight: 29 KB
Volume: 28
Category: Article
ISSN: 0931-7597
DOI: 10.1002/chin.199716153

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✦ Synopsis

Synthesis

of 2-Azatricyclo(5.2.1.04,10)decanes and 2,5-Diazatricyclo(5. 2.1.04,10)decanes by Intramolecular Azomethine Ylide Cycloadditions.

-The title reaction proceeds stereoselectively with all-cis stereochemistry of the products, which are of interest in natural product synthesis and medicinal chemistry. -(OVERMAN, L. E.; TELLEW,

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