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1-Phenylthio-3-vinyl-3-cyclohexenol, a New Reagent for Bis-Annelation of Silyl Enol Ethers.

✍ Scribed by Olga Konstantinova; Florence C. E. Saraber; Enrique Melguizo; Ben J. M. Jansen; Aede de Groot


Publisher
John Wiley and Sons
Year
2006
Weight
33 KB
Volume
37
Category
Article
ISSN
0931-7597

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ChemInform Abstract: Heck Reactions Star
✍ M. WEBEL; H.-U. REISSIG πŸ“‚ Article πŸ“… 2010 πŸ› John Wiley and Sons βš– 35 KB πŸ‘ 2 views

Heck Reactions Starting from Silyl Enol Ethers -A Simple One-Pot Nonaflation-Coupling Procedure for the Synthesis of 1,3-Dienes. -Silyl enol ethers (I) and (VIII) react with perfluorinated butanesulfonyl fluoride in the presence of catalytic amounts of Bu 4 NF. The resulting nonaflates are directly