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1-PHENYL-2-TETRALONE AND 1-PHENYL-2-NAPHTHYLAMINE

✍ Scribed by ZAUGG, HAROLD E.; FREIFELDER, MORRIS; HORROM, BRUCE W.


Book ID
126236184
Publisher
American Chemical Society
Year
1950
Tongue
English
Weight
236 KB
Volume
15
Category
Article
ISSN
0022-3263

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N-phenyl-1-naphthylamine
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## Abstract N‐Phenyl‐2‐naphthylamine has been synthesized (1) with ^14^C in positions 1, 4, 5 and 8, (2) with ^13^C in position 8 (small amounts of [1‐^13^C] naphthalene and 2‐[8‐^13^C]naphthylamine are formed as by‐products), and (3) with the N‐phenyl nucleus uniformly labelled with ^14^C.

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The title compound, C 17 H 12 Cl 2 O, has a cyclohexenone ring in the half-chair conformation. The aryl ring in the side chain attached to the tetralone ring is twisted out of the plane of the ,-unsaturated ketone plane as a result of non-bonded interactions.