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1-pentyl 4,6-dihydroxy-5-nitrosopyridine-3-carboxylate: A new reagent for the determination of osmium

โœ Scribed by Reeves, Roy R. ;Williams, Howard P. ;Bedenbaugh, John H.


Publisher
Springer-Verlag
Year
1977
Weight
195 KB
Volume
67
Category
Article
ISSN
0344-838X

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2-Fluoromethyl-4,4,6-trimetiiyl-1,3-oxas
โœ Timothy B Patrick; Sedigheh Hosseini; Satinder Bains ๐Ÿ“‚ Article ๐Ÿ“… 1990 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 181 KB

The title compound easily forms an anion on treatment with nbutyllithium. The anion reacts with electrophiles such as alkyl halides, aldehydes, and ketones. The resulting products furnish a-fluoroaldehydes after reduction and hydrolysis. ' ~-~ c 2) Electrophile (R) F 1