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1-O-Benzyl-2-O-methyl-rac-glycerol: a key intermediate for synthesis of ether glycerolipids

✍ Scribed by Anatoly N. Pinchuk; Boris I. Mitsner; Vitaly I. Shvets

Book ID: 103041634
Publisher: Elsevier Science
Year: 1991
Tongue: English
Weight: 217 KB
Volume: 59
Category: Article
ISSN: 0009-3084
DOI: 10.1016/0009-3084(91)90026-8

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✦ Synopsis

A new scheme for synthesis of saturated 1-O-alkyl-2-O-methyl-rac-glycerolipids is described. The reductive cleavage of 2-O-methyl-1,3-O,O-benzylideneglycerol with BH3.THF complex leads to 1-O-benzyl-2-O-methyl-rac-glycerol, which is a key in intermediate for the facile preparation of 1-O-alkyl-2-O-methyl-rac-glycerol and derivatives.

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