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1 H NMR Relaxation Study of the Gelation of Syndiotactic Poly(methyl methacrylate) in Toluene

✍ Scribed by Ruytinx, Bert; Berghmans, Hugo; Adriaensens, Peter; Storme, Liesbeth; Vanderzande, Dirk; Gelan, Jan; Paoletti, Sergio

Book ID: 126879602
Publisher: American Chemical Society
Year: 2001
Tongue: English
Weight: 81 KB
Volume: 34
Category: Article
ISSN: 0024-9297
DOI: 10.1021/ma000958e

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## Abstract Association of syndiotactic (s) poly(methyl methacrylates) (PMMAs) in toluene, benzene, and acetonitrile has been studied by NMR spectroscopy, osmometry, and viscometry. It was found that in solutions of highly syndiotactic PMMA in toluene, most of the polymer exists in the associated s