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NMR-study of structure and dynamics of associates of syndiotactic poly(methyl methacrylate) in toluene

✍ Scribed by Jiří Spěváček; Bohdan Schneider

Publisher
Springer
Year
1980
Tongue
English
Weight
318 KB
Volume
2
Category
Article
ISSN
0170-0839

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📜 SIMILAR VOLUMES

NMR spectroscopic, osmometric, and visco
NMR spectroscopic, osmometric, and viscometric study of association of syndiotactic poly(methyl methacrylate) in dilute solutions
✍ Spěváček, J. ;Schneider, B. ;Bohdanecký, M. ;Sikora, A. 📂 Article 📅 1982 🏛 Wiley (John Wiley & Sons) 🌐 English ⚖ 562 KB

## Abstract Association of syndiotactic (s) poly(methyl methacrylates) (PMMAs) in toluene, benzene, and acetonitrile has been studied by NMR spectroscopy, osmometry, and viscometry. It was found that in solutions of highly syndiotactic PMMA in toluene, most of the polymer exists in the associated s

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The present article considers the coil-to-globule transition behavior of atactic and syndiotactic poly(methyl methacrylates), (PMMA) in their theta solvent, n-butyl chloride (nBuCl). Changes in Rh in these polymers with temperature in dilute theta solutions were investigated by dynamic light scatter