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1 H ,1 H ,2 H ,2 H -Perfluoroalkyl-Functionalization of Ni(II), Pd(II), and Pt(II) Mono- and Diphosphine Complexes: Minimizing the Electronic Consequences for the Metal Center

โœ Scribed by de Wolf, Elwin; Mens, Ad J. M.; Gijzeman, Onno L. J.; van Lenthe, Joop H.; Jenneskens, Leonardus W.; Deelman, Berth-Jan; van Koten, Gerard


Book ID
126901462
Publisher
American Chemical Society
Year
2003
Tongue
English
Weight
141 KB
Volume
42
Category
Article
ISSN
0020-1669

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Radical-initiated PฯชH addition of (1S,2S)-C 5 H 8 (PH 2 ) 2 to cycloalkenes gave bis(secondary phosphanes), (1S,2S)-C 5 H 8 [P(H)C n H 2nฯช1 -cyclo] 2 (n = 5ฯช8), as mixtures of R P ,R Pะˆ , S P ,S Pะˆ , and R P ,S Pะˆ diastereomers. The three diastereomers of the peralkylated chiral P 2 ligand