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P-Alkylated (1S,2S)-Cyclopentane-1,2-diylbisphosphanes with Four Stereogenic Centers and Some Group 10 Metal(II) Complexes Containing the (1S,2S)-C5H8[P(CH3)C8H15-cyclo]2 Ligand

✍ Scribed by Lutz Dahlenburg; Volker Kurth

Publisher: John Wiley and Sons
Year: 1998
Tongue: English
Weight: 612 KB
Volume: 1998
Category: Article
ISSN: 1434-1948
DOI: 10.1002/(sici)1099-0682(199805)1998:5<597::aid-ejic597>3.0.co;2-e

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✦ Synopsis

Radical-initiated PϪH addition of (1S,2S)-C 5 H 8 (PH 2 ) 2 to cycloalkenes gave bis(secondary phosphanes), (1S,2S)-C 5 H 8 [P(H)C n H 2nϪ1 -cyclo] 2 (n = 5Ϫ8), as mixtures of R P ,R PЈ , S P ,S PЈ , and R P ,S PЈ diastereomers. The three diastereomers of the peralkylated chiral P 2 ligand

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