Recent publications (3,4) have reported reactions which are potentially examples of 6-electron processes (5) involving migration of a bromine atom. Thus Salaun and Conia (3) reported the
1-Ferrocenyl-2-iodoethanone
✍ Scribed by McAdam, C. John ;Robinson, Brian H. ;Simpson, Jim
- Publisher
- International Union of Crystallography
- Year
- 2006
- Tongue
- English
- Weight
- 298 KB
- Volume
- 62
- Category
- Article
- ISSN
- 1600-5368
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📜 SIMILAR VOLUMES
The molecular structure of (I). Displacement ellipsoids are drawn at the 30% probability level.
In a search for potent fungicidal agents, the title compound, [Fe(C 5 H 5 )(C 17 H 18 N 3 O)], has been synthesized and its singlecrystal structure determined. It has proven that a bulky group, such as ferrocene, close to the triazole ring results in a decreased fungicidal activity.
In the title compound, [Fe(C 5 H 5 )(C 20 H 23 )], the two fivemembered cyclopentadienyl rings are nearly parallel, with a dihedral angle of only 3.8 (1) . The dihedral angle between the indenyl plane and the substituted cyclopentadienyl ring is 58.1 (2) .