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1-Diphenylphosphino-2-methyl-1,2-dicarba-closo-dodecaborane(12)

✍ Scribed by Kivekäs, R. ;Sillanpää, R. ;Teixidor, F. ;Viñas, C. ;Nunez, R.


Book ID
114511152
Publisher
International Union of Crystallography
Year
1994
Tongue
English
Weight
453 KB
Volume
50
Category
Article
ISSN
0108-2701

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1,2-Bis(diphenyl­phosphino)-1,2-dicarba-
✍ Zhang, Dao-Peng ;Dou, Jian-Min ;Li, Da-Cheng ;Wang, Da-Qi 📂 Article 📅 2006 🏛 International Union of Crystallography 🌐 English ⚖ 130 KB

The title compound, C 26 H 30 B 10 P 2 , was synthesized by the reaction of 1,2-dilithiocarborane with diphenylchorophosphine in diethyl ether. The molecular symmetry of the molecule deviates from C 2v because of the different mutual orientations of the phenyl groups. The two P atoms of the -PPh 2 g